As others have mentioned, different metals and the propensity to work them require differing amounts of knowledge. They also require
vastly different amounts of
fuel.
Egypt was fuel-starved. Its only arable region is along the banks of the Nile river, a band at best a few kilometers wide, which to this day remains the population center of the country. Wood came either from up-river (rarely), or from other points in the Mediterranean. I'm weak on the specifics, but the ancient references to the Pines of Lebanon bear on this.
Meteoric iron is valuable because it is molecularly pure iron. It's essentially supernova ash -- what's left after the final stages of stellar fusion result in least-nuclear-potential atoms, iron and nickel. It's molecularly pure because it hasn't rusted -- in space, no one can hear you rust, either.
Iron on Earth is rusted in large part due to the early stages of biological evolution in which the great oxygenation event occurred, and with it the great rusting -- oxidation of what was, at the time, pure molecular iron lying on Earth's surface, with the now newly-available oxygen. Semlting is a de-oxidation process.
Many of the great iron ore fields are also the result of biological activity -- early-stage microbial life using iron (I am not sure of how specifically) in its own metabolic processes, and depositing large stratified bands of iron as a result. These ores are 1-3 billion years old. As with other resources, they're among those humans have been tearing through, literally, at an amazing clip over the past 200 years.
Iron smelting prior to the age of coal was performed using charcoal. Charcoal kilns -- you can find pictures online -- are large beehive-shaped stone structures which were stacked full of wood and lit afire. The wood was pyrolised but not combusted, pushing out the impurities. This is close in chemical properties to coal which is, in essence, wood subject to somewhat longer pyrolisation processes, as well as geological formation.
And the modern switch from charcoal to coal (originally sea-coal, opportunistically harvested chunks broken from open seams along the English seashore) occurred as what had been a heavily-forested Britain was exhausting its own renewable wood resource and turned instead to coal. An activity which already by the late 1700s was recognised as unsustainable (John Williams, A Natural History of the Mineral Kingdom, 1789).
Discussed at greater length in William Stanley Jevons' The Coal Question:
https://archive.org/stream/coalquestioninqu00jevo#page/14/mo...