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You sure can. The normal fair weather voltage gradient in the atmosphere is around 100V per metre. When there are close thunderstorms this increases. Unfortunately for energy collection air is quite insulative. That's also fortunate in that we don't get shocks all the time just from standing around in an environment where your head is 200V different than your feet. Popular Science once ran an article that showed how…
What's required for a tower to become electrified from the air? I feel like I've played on other metal towers in my life that were inert...
Once you were on the tower you wouldn't notice anything. You would have to get between the ungrounded tower and ground.