Kepler has been revolutionary in discovering these 700 odd planetary systems, but we can't even begin to imagine what surprises await for when we point the James Webb Space Telescope at them. One of JWSTs mission objectives is to study the planetary systems discovered by Kepler, and the origins of life. http://en.wikipedia.org/wiki/James_Webb_Space_Telescope#Miss...
What specifically will the telescope tell us about this exo-planets? It surely can't image them directly, right?
It's large aperture infrared sensors will have an unobstructed view of the universe (unlike Hubble which is in low earth orbit, and so only gets 90 minute windows of observation).
Basically, using IR spectroscopy we will be able to analyse the atmospheric composition as well as the thermal emissions of exoplanets.
Finally, JWST won't be limited to a small, fixed field of view like Kepler.