Earlier quoted context omitted.
FWIW: given the extraordinarily complicated mechanical design, merely reaching orbit is the "easy part". The real imagined disasters won't happen until the mirrors assemble.
The Ariane 5 is batting 106 for 111 which is pretty good odds and perfectly respectable for a heavy lift vehicle... but not so much so that I don't wish it was launching on an Atlas 5 instead.
Now, both Ariane 5 and Atlas 5 are extremely reliable, mature rockets.