Earlier quoted context omitted.
TrueCrypt does exactly that. The problem is that everyone knows about it; so the police will always suspect there is a second hidden section.
But if you've done it right, they can't prove it. In US law, you can't convict someone criminally because you suspect they're withholding information, you have to be able to prove it beyond reasonable doubt.
Your ability to defend against tactics like this is 100% dependent on the size of your bank account, which, by the way, may also be compromised if the prosecutors can convince the right people that you made any money at all on your illegal activities.
This is why I am mostly blasé about things like TrueCrypt's capabilities or this particular part of the law or what-have-you. If you're doing something illegal involving a computer, you're already screwed anyway -- unless you're independently wealthy and have some serious connections.