Earlier quoted context omitted.
Crystals are by definition ordered by a very regular pattern. I don't fully understand the mechanism, but I'm not surprised that it exists.
Glass is not a crystal. Not sure what I was thinking. No idea why its surface is reflective.
This is how anti-reflective coatings work-- by "smoothing" the transition using materials that have intermediate refractive indices. E.g., flourite coatings on glass lenses.