My only experiences with Guido when he was a Googler were incredibly unpleasant.
(This was years ago, and i don't have the email exchange anymore, so i'm doing my best to describe it from memory)
I reported a bug I had debugged pretty heavily and believed was likely a bug in the appengine datastore (this was before it was publicly available, IIRC), with a fairly detailed repro recipe, etc.
(I was not on the appengine team, just building an app)
I had debugged all the client side code all the way down to the rpc to the datastore server and was positive there was nothing weird going on there at all.
Within a minute or two of me sending the email to the email alias , he replies with "This must be a bug in your code, that can't happen". He didn't even look at it (i looked at the logs)
I replied with "I agree it should be impossible, but if you could look at it for a second, i think you'll see that it's not and is actually happening. The code is very simple, etc".
He says "I don't have time to fix your code".
So i spend the time and reduce it to a simple, 20 line piece of completely obvious code (IIRC i believe it had no real code except to instantiate the class and store it in the datastore) with no dependencies.
and say "here, i took the time to try to make it as clear and obvious that this is really not a bug in the code, because there is no real code here"
He replied with something else abrasive and dismissive.
Then, about 20 minutes later, one of his teammates replies with basically, "oh shit, this is bad".
(Because what i had discovered turned out to have caused data loss that they couldn't automatically fix. The could get the data back from restores, but it wasn't clear what to do with it, you needed intervention from a user)
Honestly, it would have been better for him to not respond at all.
(he was not the on-call team member at the time anyway)
We all have our bad days/times of course (i definitely did!), so i do hope he's found more inner peace than he had back then.
But yeah.