In any stellar system like ours, where oxygen is the most abundant element, except for the hydrogen and helium that are contained mostly in the star and in the big planets, almost all metals are completely oxidized (with the exception of the siderophile elements submerged into the cores of the planets, because of their great density) and the amount of metallic substances with a natural origin that can be found in the accessible surface layers of the planets is negligible.
Reducing the oxidized metals requires much more energy than reducing non-metals like carbon, nitrogen and sulfur (which is what the living beings do to make their structural materials), and preventing the reduced metals to spontaneously become oxidized again is very difficult.
This is why no living beings have succeeded to use metallic materials before the humans, and the latter have succeeded to do this only after mastering the fire, which is the other thing that the non-human living beings have not succeeded to do.
There exists a second class of stellar systems, where there is more carbon than oxygen, so almost all oxygen remains bound in carbon oxides, while most other elements are present as carbides, instead of oxides, like in the Solar System. These are much more rare than the stellar systems of the Solar System type and in such stellar systems the chemical composition of the planets would be extremely different from the planets of the Solar System. Because there is no detailed information about such a stellar system (due to their distance), there is very little knowledge about whether there would be conditions in such a system for the appearance of life and how could that evolve. If there is any chance for primitive life forms to use metals in their structures, that would happen only in such stellar systems.