Thank you for sharing what you know. I'm aware of these issues. My personality is irrelevant to them; they are what they are whether the person talking about them is an arrogant asshole or not. I'm puzzled as to why you thought I'd be interested in discussing whether or not I'm an arrogant asshole, really!
Your calculation of solar capacity is off by a factor of a million; 500 megawatts at 200W/m² is 2.5 km², not the 2500 km² you say (the size of Yosemite National Park), which would be 500 terawatts, roughly 30 times current world marketed energy consumption. The same magnitude of error in the other direction would have led you to claim that an aluminum smelting plant requires 500 watts, less power than a household blender.
You also forgot to divide by the capacity factor; 200W/m² is the nameplate capacity, what the square meter produces in full sun, not the year-round average, which is closer to 30W/m², depending on factors like latitude, clouds, and tracking. (That increases the estimate from 2.5km² to 17km², 1700 hectares or 7 sections, the area of the city of Los Altos, California, or a quarter the area of the Curonian Spit park in Kaliningrad.)
These basic errors suggest that either you are not fully aware of the extent of your knowledge, or you are knowingly exaggerating it.
It seems like your primary objection is the intermittency of solar energy, which can be straightforwardly solved with BESS; even without lithium resources, either liquid metal batteries or nickel–iron batteries are an adequate resource anywhere in the world. Sodium-ion batteries are another scalable form of BESS that does not depend on scarce elements; a 200MWh utility-scale sodium-ion battery came online a year ago in Qianjiang: https://www.energy-storage.news/first-half-world-largest-200... but plausibly nobody outside of China knows how to do this.
There are straightforward solutions to the problems you're describing, even without BESS; many haven't been developed beyond the lab scale because they aren't economically competitive with the established approaches you're describing. In a hypothetical blockaded country, those alternatives wouldn't be competing with cheap fossil fuels. In practice, though, BESS is plenty.
Silicon purification to solar grade is not simply an electrolytic process, as you incorrectly imply; it requires a series of refinement steps to become PV-grade silicon.
In the case of glassmaking, the necessary technology is already well developed. An all-electric glassblowing pilot plant entered production last year in Cognac: https://www.youtube.com/watch?v=FuK8f4cB7Ps. And you can buy off-the-shelf glassmaking furnaces for mass production: https://www.hornglass.com/products/melting-furnaces-and-equi...
Electrically heated furnaces are more controllable and versatile, which is why they are universally used in laboratory glassmaking. Unlike the case with aluminum, fossil fuels are nothing but trouble for glassmaking; limited adiabatic flame temperatures, glass-batch contamination from fuel impurities, and the unfortunate necessity to vent flame-fired furnace to the atmosphere are problems glassmakers have had to overcome in order to use cheap energy from fossil fuels, not benefits.
Carbon is probably the only possible electrode material for aluminum production, although zirconia has been suggested. The net reaction is Al₂O₃ + 3C → 2Al + 3CO, consuming about 700kg of carbon per tonne of aluminum produced. Fortunately such small quantities of carbon are not difficult to obtain, and in extremis it would even be bearable to obtain them via direct air capture; we're talking about hundreds of grams of carbon per 300-watt solar panel, so a single tree contains enough carbon to smelt the aluminum for a megawatt or so of panels.
Mining is almost entirely electrified already; attempting to run fossil-fuel machinery in an underground mine shaft, or even an indoor warehouse, poses the kind of risk of asphyxiating workers that is normally considered unacceptable except in, for example, Russia. Gargantuan strip mining machinery like the Marion 8750 is largely electric for the same reasons that diesel locomotives are electric.
Thank you for a productive, if gratuitously insulting, exchange of views!