Earlier quoted context omitted.
> Maybe I have the benefit of giant shoulders, but this seems like a fairly mundane observation. It is not mundane, and it is also not right, at least for entropy in Physics and Thermodynamics. > High-entropy states are those macrostates which have many corresponding microstates. That is how you deduce entropy form a given model. But entropy is also something that we can get from experimental measurements. In this ca…
Maybe the experimental apparatus is not objective. The quantities we choose to measure are dictated by our psychological and physiological limitations. The volume of a container is not objectively defined. An organism which lives at a faster time scale will see the walls of the container vibrating and oscillating. You must convince the organism to average these measurements over a certain time scale. This averaging t…
No. The enthalpy changes measured by a calorimeter are not dependent on our psychological limitations.
> The volume of a container is not objectively defined.
Yes, it is, for any reasonable definition of "objective". We know how to measure lengths, we know how they change when we use different frames of reference so there is no situation in which a volume is subjective.
> An organism which lives at a faster time scale will see the walls of the container vibrating and oscillating.
This does not matter. We defined a time scale from periodic physical phenomena, and then we know how time changes depending on the frame of reference. There is no subjectivity in this, whatever is doing the measurement has no role in it. Time does not depend on how you feel. It’s Physics, not Psychology.
> This is the same with other thermodynamic quantities.
No, it’s really not. You seem to know just enough vocabulary to be dangerous and I encourage you to read an introductory Physics textbook.