Earlier quoted context omitted.
Not sure I'm following. Fission reactors split uranium into smaller atoms like barium and krypton. The remaining energy that comes out as afterglow heat in the repository is a small fraction of what already came out during fission. less than 1% remains an hour after fissioning.
You have the numbers reversed. In spent nuclear fuel 96% of the mass is the remaining uranium is still usable. Spend nuclear fuel (=LEU) used in these reactors have almost all potential energy left. You can use them if you close the nuclear fuel cycle with fast neutron reactors. The downside of it is that they FNR's are also good for making fuel for nuclear weapons.
Reprocessing can recover some plutonium, which can be reused (once more) in MOX fuel. Spent MOX fuel cannot be reprocessed further for use in today's thermal reactors, though.