The Sydney Opera House is a good example, actually. It's an iconic building. Australia is frequently represented by a picture of the opera house in front the the harbour bridge, possibly with Uluru in the middle distance (it's just outside Sydney, apparently). There's just one problem. It's not a very good opera house . The structural requirements make it impossible to have an ochestral pit for the musicians, and the…
I'm not claiming it is a great opera house, but it is a very good example of using modern building tools.
When Utzon died, one of our (Danish) newspapers explained that the required maintenance is now necessary because the architects original plan to cap the "top-seams" with metal was judged too expensive, and some plastic-sealant ("Caulk" ?) were filled into the seam instead, and that has allowed moisture to seep into the construction. I have no idea if this is true or not.