MSSQL has some problems, some of which the post talks about. However, I tried pg out, planned to use it instead of MSSQL.
1. HA, via replication, clustering, etc. are all fantastic as well as easy and trivial to setup. Once PG can offer a simple little wizard and setup replication, or shared-nothing clustering with automatic fail over, awesome. Or even tx log shipping with a few clicks.
Instead, last I tried (9.0 I think), pg drops you off with some weird system that makes you run shell as a specific user, where you run generic sounding commands. Oh and some default config that seemingly has some bad defaults you probably should change.
2. Overall, MSSQL makes it easy to run a DB. I was doing a billion transactions a day (each which wrote to a few tables and also included a real ACID balance update), and I didn't need a full time DBA or have to have particularly awesome experience beforehand. With pg, I sorta got somewhere, but I had little confidence
3. Development is far superior on MSSQL. Supporting other languages is a null point, because they aren't running as part of the query execution engine. That is, there's no real difference in using Python inside PG versus an external client, as far as I could tell. You still had to submit queries and make a transition. So TSQL seemed far nicer to work with than plpgsql. Although, the record types in pg were much nicer I'll admit. Another annoyance: pg didn't offer multiple returnsets in many situations. This made it awkward to run a sub function that needed to return results from different tables as separate queries. And the perf tools and UI was just so, so much better.
4. There'd be strange "little" features you'd just expect to be there, like materialized views, which pg simply does not have. Pg still lacks materialized views. The current implementation is essentially pointless, as it doesn't update the view automatically.
I'm very much for PG, and believe it's an important project and am trying to use it for future development. Much because Microsoft went back on its word that it wouldn't move to an Oracle-style licensing where you pay for CPU power instead of just sockets. They've also made questionable decisions with Enterprise vs Standard, putting extra cumbersome limitations. They aren't adding features like JSON or arrays quickly. And also, I think it's important to run open source and try to make sure free systems stay viable.
But MSSQL has a lot going for it, and the ease of use and built in HA options don't even seem like goals for PG. If licensing weren't in the way, and I just wanted an easy system that was capable but didn't require lots of time, MSSQL makes a strong choice.