Earlier quoted context omitted.
It is powerful, but I'm not sure it is a good idea. Other languages have it, and there is lots of experience in all the ways things go wrong in the real world. I'm inclined to say you should hand write this code because eventually you will discover something weird anyway.
I think this is a very bad take -- once you write it by hand you have to manually keep it in sync with the actual struct and ensure you made no mistakes. Reflection guarantees 1-1 future-proof mapping with the actual C++ struct, avoids boilerplate, and ensures that the serialization logic is correct.
That is if you are worried about doing this by hand reflection is not the answer, something like protobuf where your data structures are generated is the answer.