Well, well. Kind of surprised to see this really good tool that should have been made available a longer time ago since the approach is quite sound. When the data container is understood, the deduplication is far more efficient because now it is targeted. Licensed as BSD-3-Clause, solid C++ implementation, well documented. Will be looking forward to see new developments as more file formats are contributed.
Specialization for file formats is not novel (e.g. 7-Zip uses BCJ2 prefiltering to convert x86 opcodes from absolute to relative JMP instructions), nor is embedding specialized decoder bytecode in the archive (e.g. ZPAQ did this and won a lot of Matt Mahoney's benchmarks) but i think OpenZL's execution here, along with the data description and training system, is really fantastic.
Like you mention, the expandability is quite something. In a few years we might see a very capable compressor.