Can't help but wonder if this is a solution searching for a problem. Landfills already have protections against leeching into the surrounding environment. And we aren't going to plausibly run out of space for landfills in the foreseeable future (images from Wall-E notwithstanding). Isn't plastic basically inert once it gets to a landfill anyway? Even if it takes centuries to break down, who cares? IMO we'd be better…
And IMO there’s much upside to pursue multiple avenues to desired solutions, rather than making choices to eliminate potentially contending solutions too early.
Mother nature herself provides pretty much exactly that template for evolution. So if we want to save nature, why not use that same approach? It seems to have served the survival of life on our planet rather well.