Anybody who thinks they know for sure that slack can't possibly be worth $16B should go back and read some threads from around the Facebook IPO (like this one https://news.ycombinator.com/item?id=4320585 ). It's very easy to write reasonable sounding things - making accurate predictions about the future is much harder.
Yeah, I'm going to go out on a limb here and venture a guess that Slack is going to do very well for itself, though it may dip and swoon over the next couple years before it reaches that point. An even more applicable comparison is the HN thread about the Dropbox announcement. "What? This is just [IRC|rsync] with gimmicky bells and whistles."
And even though blogging, threaded forums for discussion, chat rooms, email, etc. all already existed, it still has been enormously successful despite seemingly being drastically inferior to any of them in every way.
Things don't have to be better or even good to succeed, they don't even have to be difficult to clone. A bit of luck at the right time followed by a snowball effect and they can be huge. $28 billion for a textfield? Sure, why not?