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Why is desalination so difficult?

practical.engineering

41–50 of 644 posts

Re: Why is desalination so difficult?

#41
post #33

Stupid question time, why not expose the sea water over a larger area and expose to sunshine? There's plenty of room in the UAE for this, somebody is even building a wall that could hold the water which could be dual purpose and act as cooling via evaporation...

Larger area than the oceans?

We'll no but a super long wall facing south might do the trick...

Re: Why is desalination so difficult?

#42
post #36
post #20

Earlier quoted context omitted.

In an operation like that, do they heat the syrup under low pressure to reduce the boiling point of water?

I'd guess that if anything they'd increase the pressure to raise the boiling point. That way things dissolve in it faster and the water doesn't evaporate away.

On this topic the 14 minute episode "How Do They Make Maple Syrup?" from the PBS chemistry show 'Reactions' may be of interest:

https://youtu.be/nSRCDiKMEJc

Re: Why is desalination so difficult?

#43
post #9

Probably very dumb idea, but would it be feasible to just pump and sprinkle sea-water on hot, dry desert and let it naturally evaporate, and then collect it as fresh rainwater back? i.e. how much water would you need to evaporate to have a noticeable increase in rainfall?

In other words, you want to salt the land? Isn't that what marauders do when they want to destroy an area permanently?

Re: Why is desalination so difficult?

#44

Can I shower in salt water? Then all I need to do is desalinate drinking water. “Distributed” home desalination for drinking water seems like the best approach in my mind, then people can pay as much or as little they need, but I have no real data to back this up.

> Can I shower in salt water?

You at least need special soap: https://en.wikipedia.org/wiki/Saltwater_soap

Re: Why is desalination so difficult?

#46
post #36
post #20

Earlier quoted context omitted.

In an operation like that, do they heat the syrup under low pressure to reduce the boiling point of water?

I'd guess that if anything they'd increase the pressure to raise the boiling point. That way things dissolve in it faster and the water doesn't evaporate away.

The goal is to evaporate the water away. For every liter of finished syrup, you need to get rid of approximately 40 liters of water.

Re: Why is desalination so difficult?

#47
Is it just me, or did this article dance around the question?

I am not a physicist but let me give it a stab: except for a few specialized steps like UV or oxidizing heavy metals, most filtration is mechanical. A series of filters with smaller and smaller pores capture more and more of the mess in the water like bacteria and particulates while UV breaks down viruses, the oxidizer precipitates out metals, and so on.

None of those methods work with salt. Salts in general disassociate through ion-dipole interactions - the water dipoles essentially rip the ionic compound apart and surround each ion in what is called a hydration shell. They're bigger than bare water molecules but not much bigger - much too small to target with pore size. This shell also puts them in a thermodynamically stable state and it takes energy to "jostle" the water molecules away from the ions either through evaporation, distillation, or through another chemical reaction that precipitates out the ions.

As it turns out, doing that takes a lot of energy, so we use reverse osmosis as a cheaper alternative: we exploit the hydration shell of the ions by putting them behind a semi-permeable membrane with very small pores, "nanopores" if you will. The pores are too small for water to cross normally, but under high pressures bare water molecules can be forced through the pores while the ions trapped in their shells remain and concentrate into a brine. It takes less energy but produces a concentrated liquid waste stream that must be disposed of.

Someone please correct any mistakes I've made

Re: Why is desalination so difficult?

#48

Can I shower in salt water? Then all I need to do is desalinate drinking water. “Distributed” home desalination for drinking water seems like the best approach in my mind, then people can pay as much or as little they need, but I have no real data to back this up.

Yes, you can shower in salt water, but you won't feel as clean in the end. You also use water for washing clothes and dishes, as well as washing your hands, watering plants, and various other tasks, for which salt water is unsuitable.

Re: Why is desalination so difficult?

#49
post #31
post #3

It's not difficult. It's just energetically uphill. Undoing entropy costs energy. Second Law of Thermodynamics.

The thing is, it doesn't have to be. The energy released by mixing salt into water is small, around 3.9kJ/mol. Molar mass of salt is 58g/mol, and the average sea water salinity is around 3.6% So a cubic meter of sea water will have 1000*0.036/0.058=620 moles of salt, and it'll require 2.4MJ of energy to remove the salt in a perfect desalinator. In more common units, 2.4MJ is about 0.75 kWh. Around here electricity is…

> cubic meter of sea water will have 1000*0.036/0.058=620 moles of salt, and it'll require 2.4MJ of energy to remove the salt in a perfect desalinator. In more common units, 2.4MJ is about 0.75 kWh.

> A thousand liters takes about 3kwh.

So, if those numbers are right, desalination is currently at about 25% of theoretical energy efficiency. Is that correct?

Re: Why is desalination so difficult?

#50
I like the analogy at the end regarding nuclear power vs piping in water from freshwater sources. The upfront costs are high, but over time it would be cheaper than desalination, but due to short term governments and borders, it's hard to justify the upfront costs. So instead we are somewhat stuck with more expensive short term solutions.
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