Some context for people younger than me: This was a Big Thing On The Internet back in 2000. It was lovely, and it was where I discovered how a bunch of motivated nerds on the internet could make a dent. So anyway, the thing was DVDs were pretty new, and DVDs had "region protection". Cutting corners, this means that data on DVDs could be encrypted with different keys depending on which continent you were on, to allow…
"CSS" in this case stands for "Content Scrambling System." It may well predate the common use of CSS (stylesheets) on the web. They both originated around 1996.