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What are “actual pictures” of atoms actually pictures of?

askamathematician.com

41–50 of 57 posts

Re: What are “actual pictures” of atoms actually pictures of?

#41

Well, as the article points out, the things being imaged are most definitely actual atoms. The only thing TFA is nitpicking about is that light isn't used to image those atoms. This is about as interesting as pointing out the fact that an ultrasound picture of a baby isn't an "actual picture", since we use sound instead of light to make the image.

No I disagree. An ultrasound picture of a baby accurately reflects the actual form of the baby. A Scanning Tunneling Electron Microscope does not accurately reflect the form of an atom because it simply uses an artificial dot to represent the presence or absence of an atom. In short, the "map" that STM's give us is abstracted from reality and does not accurately portray an atom (in large part because STM's still simp…

Well, we can image molecular orbitals using STM [1], which I'd say is one of the best ways to represent the shapes of atoms.

[1] https://physics.aps.org/featured-article-pdf/10.1103/PhysRev... (open access)

Re: What are “actual pictures” of atoms actually pictures of?

#42
I cannot see (pun intended) how "normal" seeing is fundamentally different. One basically sees by measuring their interactions with photons and deducing how something "looks like" vs. measuring interactions with electrons in STM and making a similar deduction.

Re: What are “actual pictures” of atoms actually pictures of?

#43
post #5

Well, as the article points out, the things being imaged are most definitely actual atoms. The only thing TFA is nitpicking about is that light isn't used to image those atoms. This is about as interesting as pointing out the fact that an ultrasound picture of a baby isn't an "actual picture", since we use sound instead of light to make the image.

The concept of the scanning tunneling microscope is so simple and ridiculous that it was probably thought of and dismissed long before someone built one. "You're going to image atoms by dragging a tiny needle across them"? Yet that's pretty much how it works. The first one was built in 1981, but one could have been built in the 1950s. Piezoelectric crystals were known. Raster scanning circuits were known. Feedback ci…

How do you verify that the tip is indeed one atom sharp without already having something like an STM?

Re: What are “actual pictures” of atoms actually pictures of?

#44
post #38
post #24

Earlier quoted context omitted.

Isn't it possible to make an image using light, but by computing the "real" image from the interference pattern (of a single non-repeating atom/structure)? And if there is more than one solution, then perhaps by using images from multiple angles, or with different wavelengths?

Isn't that basically what X-ray crystallography is (taking the liberty to include X-rays as "light")? Though with the (significant) restriction that it only works for repeating crystal structures, not unique individual targets...

Yes, so my question is if we can do it also on individual targets.

Re: What are “actual pictures” of atoms actually pictures of?

#45
post #28
post #25

Earlier quoted context omitted.

How do you know if your tip is one atom wide or not? Also, what would the shape of the tip look like if you drew it? I'm wondering what kind of general angles the surface has. Is it like a cone with a single atom at the tip? What kind of slope?

The only real way to know if you had a single atom tip was to image a known surface. If the image was junk you probably had some funky tip states going on. HOPG (graphite) was the standard we typically used. A good tip could be just about anything, from a nice cone to really jagged. One problem was any of the methods one has to view the tip can't actually resolve the single atom that is doing the imaging.

Yeah, we used to use graphite (as flat as we could get it, tried to ensure we had a single surface) to see how good it was. You could tell how good it was from how much noise you got and therefore how good your image was.

Re: What are “actual pictures” of atoms actually pictures of?

#46

Earlier quoted context omitted.

I worked in the lab at the Nation Physical Lab in the UK that had the low pressure + low temperature STM, we used to make the tips by dipping the ends in a very strong solution of NaOH. You relied on the surface tension as it dissolved to produce you a very sharp tip. Surprisingly easy.

Cool. I know people also buy tips, but they're expensive. For really cool stuff, check out the CO functionalized tip AFM coming out of IBM in Zürich: https://www.zurich.ibm.com/st/atomic_manipulation/pentacene.... The AFM I used was mainly for teaching the concepts, so they wanted simple, cheap, low risk => strong NaOH was out. The technique back then was, somehow, cutting at about 45° angle and twisting the pliers t…

TBH, more people were using AFMs than STMs, because they're cheaper (I think) and the fact that the STM is based on conductivity limits what can be imaged.

Getting pictures of atoms is nice, but sometimes you want to image molecules, especially organic ones (tricky to do in a STM).

Re: What are “actual pictures” of atoms actually pictures of?

#47

I love that offhanded comment about how the helical structure of DNA is not at all obvious from that crystallography. All the more impressive then, the history of that discovery.

Like many things about the article it's hard to tell when the author is joking.

Knowing DNA was helical from the fiber diffraction images (not crystallography- they were working with DNA fibers, not crystals) was actually "obvious". A helix forms a distinctive cross pattern, this can be (and was) predicted easily from diffraction theory applied to a helical structure.

Re: What are “actual pictures” of atoms actually pictures of?

#49
post #11
post #7

One of my first jobs out of college was doing manual chip layouts (which will give you some idea of how old I am). Once the layout was done, the design was sent to a "mask house" which would print the layout onto a series of glass plates (the "masks") which were then used in the chip fabrication process. When the masks for my first chip came back I popped one of them into a bench microscope to see what it looked like…

What era of chip layout was this? I'm surprised that manual chip layout was still being done when chip features were that small. I look at 1970s chips a lot, and the features are easily visible under a microscope, as they are much larger than wavelength-sized.

At Motorola, in MCU, they (we?) were still doing some manual layout (not much, but still...) on 8-bit and 16-bit core products as late as 1989. Of course, none of the more advanced CPUs or soon-to-come DSPs did. IF I recall correctly (and I probably don't), depending on the fab, for those parts, we were at or around 1micron at the time.

It was an MCU, which many might call a SoC these days, but with all the timers and serial i/o and the A/D and D/A converters and PWMs - the 8-bit family (HC11) was probably around 50K transistors in an 80-pin QFP.

The HC11 had a 6809(enhanced) core. I think the 6809 was ~9K transistors, but I seem to recall that ours was a bit bigger than that. Still ~3/4 of the die was "not-CPU".

Re: What are “actual pictures” of atoms actually pictures of?

#50
post #44
post #38

Earlier quoted context omitted.

Isn't that basically what X-ray crystallography is (taking the liberty to include X-rays as "light")? Though with the (significant) restriction that it only works for repeating crystal structures, not unique individual targets...

Yes, so my question is if we can do it also on individual targets.

Ah, yes, sorry, I missed your "of a single non-repeating atom" :-)

I'm also curious -- but I wonder, would this allow for imaging anything that a scanning electron microscope can't?

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