On this: > "There's probably about 3 million households in Rwanda, and a vanishingly small number have a fridge. A refrigerator uses about 2 kilowatt-hours (kWh) of energy per day, so if we were able to get one into every household, that would add about 2 billion kWh (2 terawatt-hours, or tWh) to Rwanda's annual energy usage. That's about as much energy as there is contained in 1 million barrels of oil — and fully on…
> As you probably want to run the refrigerator at night My experience with power failures is that the refrigerator will keep the food cold enough overnight if you don't open the door. Even so, the refrigerator could make ice during the day and be an ice chest at night. No need at all for a battery.
There are numerous heating/cooling applications in which excess capacity at peak capabilities is banked for later use. Thermal energy storage for thermal energy applications is exceedingly efficient as there are no further conversion losses.
Solar power refrigeration which chills an ice block to an arbitrarily low temperature then relies on that to maintain the chilled-compartment temperature during periods of low or no power would be the obvious option.