I'm amazed he knew things in such detail. I mean who would know just how long a MAC address is? Or what the actual SYN/ACK etc tcp flags are? You just need to know what they're used for, and if you need the specifics, you'll find out with a single search. He seemed to know that as well though. Kernighan for bit twiddling algos, that kind of thing. It's a bit strange to have someone non-technical interviewing a techie…
I knew all these answers too, because I was a developer in the 1990s. There is absolutely no purpose to knowing off the top of your head how long an ethernet address is, or even what system call will retrieve an inode (his bickering over stat() "filling in" rather than "returning" was bogus, for what it's worth). The top Google search result for each of these questions has the answer. Knowing these things isn't part…
The rejoinder, of course, is that it's probably misguided to structure your recruiting around a spam filter.