You start by shipping a million tons of freight to Mars, while I do meaningful stuff at places that are not a waste of time and effort. By the time you are ready to supply fuel FOB at Mars, I have sent a million tons to places worth sending it to, instead.
Maybe my million tons of freight includes a liquid methane sump on Titan, where I don't even need to synthesize, never mind liquify the stuff; it is sloshing around in puddles everywhere. There is an interior liquid water ocean, and ice lava flows.
Seriously, if you need more delta-V for a Jupiter or Saturn trip than spaceship design A gives you, you are much better off making a spaceship design B with enough tankage to make the trip. (Maybe B is just A with an extra tank strapped on; or, a tug boosts A to escape velocity and then loops around Luna and back, aerobraking to LEO.) Park fuel depots at both low and high Earth orbits; you waste nothing by using those, unlike anything parked foolishly at Luna or Mars.
Luna, anyway, has stuff that is worth visiting, like craters in permanent shade at the south pole, and lava tubes where vapors have maybe drifted in and froze for hundreds of millions of years. Mars is the armpit of the Solar System.