I did something very similar quite recently with an old Mustek DV3000 camera that had webcam functionality. I was shocked to find out that Linux actually supports it out of the box. The quality is trash so it's not really usable, but fun messing around with it nonetheless.
The driver support makes it a lot easier to build Franken-PCs with obscure graphics cards and accessories too. You wouldn't traditionally associate Linux with just working, but in the case of older hardware it is an amazing selling point.