Qing Dynasty China had "decoupled" its currency from specie by way of the first paper-based currency I'm aware of. See: Richard von Glahn,
Fountain of Fortune: Money and Monetary Policy in China 1000-1700 (1996).
But that has absolutely nothing whatsoever to do with decoupling the actual economy from its physical foundations. Long after Qing, China remained fundamentally dependent on rice and wheat harvests (and suffered tremendous population losses, as much as 8 million deaths) many centuries later.
The wealth-tracking representation has been decoupled from any substance with intrinsic value, but the economy has not.
Put another way: you could have a monetary system in which currency was entirely backed in precious gold and silver, and introduce huge quantities of same to your economy ... without increasing the actual wealth of the nation by Adam Smith's definition, "annual produce and labour of the nation". This was precisely the situation Spain found itself in following its conquest of the Americas and importation of vast quantities of South American gold and silver.