My top 3 fun PDF facts:
1) Although PDF documents are typically 8-bit binary files, you can make one that is valid UTF-8 “plain text”, even including images, through the use of the ASCII85 filter.[0]
2) PDF allows an incredible variety of freaky features (3D objects, JavaScript, movies in an embedded flash object, invisible annotations…). PDF/A is a much saner, safer subset.
3) The PDF spec allows you to write widgets (e.g. form controls) using “rich text”, which is a subset of XHTML and CSS - but this feature is very sparsely supported outside the official Adobe Reader.
[0] For example: https://lab6.com/2