I've lost count of how many "Migrating from X to Postgres" articles I've seen. I don't think I've once seen a migrating away from Postgres article.
But yeah we did migrate our _analytics_ data to ClickHouse (while still keeping Postgres for more transactional stuff) back when I was at PostHog.
Writeup: https://posthog.com/blog/how-we-turned-clickhouse-into-our-e...