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CNC sounds like kind of a bad fit unless you're going to mill the entire frame out of a solid piece of wood -- you'd lose a lot of material to the router bit and still have to do a fair amount of finishing by hand. For mitered joints like this, there are computerized saws that can feed and cut the lumber pretty precisely, but those are very expensive. I'm not super clear on whether or not you're doing all of this by…
Hey, thank you for that comment. Those are really good tips regarding the woodworking. I'll look into one of these miter saws.
As for the look, see if you can make the wood grain go the same direction for the entire frame, rather than the grain changing from vertical to horizontal. Should make it look more attractive. To expand the appearance from there, you can sand it down and apply different oils, stains and paints.