Feels like postgres is always the answer. I mean like there's gotta be some edge case somewhere where postgres just can't begin to compete with other more specialized database but I'd think that going from postgres to something else is much easier than the other way around.
I hear MySQL can be better for some workloads?
You can be sure that PostgreSQL will be applicable for any work load that MySQL can handle, but not necessarily the other way round, so if you actually have the freedom to make a choice, go with PostgreSQL.
In particular, because PostgreSQL has a lot more features, people imply that the other one, for the lack of those features and its associated complexity, must automatically be faster. Which isn't true, neither generally, nor in special cases, since the latter one can go either way - your particular query might just run 4x on PostgreSQL. There is also no universal approach to even benchmark performance, since every database and query will have completely different characteristics.