Earlier quoted context omitted.
Not how it works. If you service has that 99.999% availability and you get a single unavailability event in a year, that's already 5 minutes of downtime completely independent from all other events that users may or may not experience, there is almost no chance of overlap between them. Users definitely notice that. And worse, events are going to be even less frequent than that and ever more noticeable and on top of t…
I think you have a misconception on what actual reliability is for more products and services. 99.999% is a solid service, 99.99999% is a hard to achieve target for enterprise software. To say Google is not the place to look for reliability is a pretty comical statement.
99.99999 is 3 seconds of downtime/year.
As you get beyond 5 nines, environmental factors begin to dominate (if the service is networked: network unavailability, if the service is onsite, power outages and weather) any reliability inherent in the service.