There are more technical details in the linked affidavit (page 6 and 7): https://www.justice.gov/opa/press-release/file/1402056/downl... They kept following transactions on the blockchain, but it's not clear how the private key became in the posession of the FBI.
Can anyone here (hn) add anything?
It seems like steps in the investigation, or process to identifying the bad guys were left out.