I've found the reason (I think) 90% of the world's semiconductor-grade neon production is concentrated in one country. Per this German government whitepaper about the noble gas industry: the USSR massively overinvested in neon capacity in the 1980's, in order to build space-based excimer laser weapons. Ukraine's extant plants date (probably) to the 1980's; they're responsible for a global oversupply that's persisted since the Cold War.
- "Neon was regarded as a strategic resource in the former Soviet Union, because it was believed to be required for the intended production of laser weapons for missile and satellite defence purposes in the 1980s. Accordingly, all major air separation units in the Soviet Union were equipped with neon, but also krypton and xenon, enrichment facilities or, in some cases, purification plants (cf. Sections 5.4 and 5.5). The domestic Soviet supply of neon was extremely large but demand low."
- "Following the collapse of the Soviet Union, global crude neon production was approximately 500–600 million l/a (= 500,000–600,000 m3/a). It was dominated by far by large-scale air separation units associated with metallurgical combines in Russia and Ukraine. Simultaneously, demand was estimated at around 300 million l/a (cf. Section 4.2). In the years between 1990 and 2012, therefore, most crude neon was not purified, but released into the atmosphere, because there was no customer base."
https://www.deutsche-rohstoffagentur.de/DE/Gemeinsames/Produ... (chapter 5.2)
For context, this would have overlapped with Energia/Buran's launch of the Polyus weapon (which was a megawatt CO2 laser).
https://en.wikipedia.org/wiki/Polyus_(spacecraft)