The way I understand this is that adding of random variables is a smoothening operation on their densities (more generally the distributions, but let me speak of densities only). A little more formally, additions over random variables are convolutions of their densities. Repeated additions are repeated convolutions. A single convolution can be understood as a matrix multiplication by a specific symmetric matrix. Repe…
Also, convolving a distribution with itself is NOT a linear operation, hence cannot be described by a matrix multiplication with a fixed matrix.