And why not use mingw gcc? Do they find somthing wrong with it? Edit Mingw-w64 its quite nice and includes gcc without all stuff cgwin does.
2. Not performant (Relative to other solutions)
3. Would be the odd man out. Literally all other development was on clang/llvm at this point.
Supporting mingw would have meant duplicating all performance/etc work for GCC.
4. Chrome also wanted other benefits that clang/LLVM would bring them (easy ability to build various forms of refactoring and analysis tooling, etc)