I have coworkers who only use 2 of chromes debugging tools: the console and the network tab. They dont know about breakpoints, mapped typescript/react files, or local overrides. Every time they come to me with some issue they're facing, I have them set up breakpoints first before we do anything. Usually that's all that we need to do, and we figure out the problem in about 5mins
On a tangent, it is weird sometimes that people not always pick the right tool for the job, even if the effort is small and the results pay off immediately. Like slicing carrots using a potato knife or even a table knife.
Chrome DevTools has that issue since it's always changing, adding new things, and they're not discoverable/learnable from inside of it.
If you had a drawer of 50 kitchen implements, would you even think to search for the mandoline slicer if you didn't already know about it?