Without doing a full-on sales pitch (I am not a salesman and do not portray one on TV), I should say that Bigcouch adds a lot of desired features to CouchDB, notably scaling beyond a single machine and sharding (which supports very large databases). We run several clusters of Bigcouch nodes in production and have done for some time, it's a thrill for me personally to see a distributed database take a real pounding and keep on trucking.
I've been meaning to try Riak myself, so you've inspired me to finally pull down the code and give it a proper examination.