"superficially simple solution to a complex problems"
--- Exactly this
While it might initially seem a bit easier to remember words vs numbers, W3W is a non-solution in many ways, many nicely described in the article.
Most critically, the W3W indicators have zero relation to actual geography. Adjacent locations have entirely different quasi-random identifiers -- there is no progressive gradation, and no indication whether two locations are adjacent or on different continents.
It does not scale, and leaves us completely dependent on a data connection and their servers to navigate.
There is also no way to figure it out from known principles. The entire system has many points of failure. With a street address, I can know which way to from seeing a couple of existing addresses; W3W - no way, need a data connection.
With Lat-Long I immediately know what part of the world I'm in, and what direction I need to move to move to get closer to my target. A GPS unit, or a simple compass and map will work great. W3W -- zero clues, and need a data connection to them.
Horrible, non-scalable, non-solution looking for a problem.
Massive marketing attempting to overcome bad technology.