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L'Affaire Siloxane

mceglowski.substack.com

1–10 of 59 posts

Re: L'Affaire Siloxane

#5
post #2

Siloxanes contaminate everything. We routinely see them on various surfaces when doing X-ray photoelectron spectroscopy.

Indeed. "Grease peaks" we called them, they were always there in basically all NMR or MS spectra I took as an organic chemist. Like PFAS or microplastics, you just can't get rid of them.

Re: L'Affaire Siloxane

#7
An interesting substory that is simultaneously reminiscent of the Fogbank story and how Hayek's "curious task" is much more broadly applicable:

  There is a good cautionary tale here from the Space Shuttle era. That vehicle 
  had heat resistant tiles that had to be attached to the aluminum belly of the 
  orbiter. A special cloth had been certified for wiping the aluminum clean 
  before applying the primer that securely bonded the tiles to the metal. After 
  years of uneventful use, tile engineers discovered that new replacement tiles 
  were no longer curing properly.
  
  A careful investigation revealed that the supplier of that special cloth had 
  changed the lubricant used in the machine that sews its hem. Minute amounts 
  of the lubricant were being deposited on the stitching, and enough of that 
  residue was getting on the aluminum skin to prevent the tile adhesive from 
  curing properly.

Re: L'Affaire Siloxane

#8
Part of my job is to keep siloxanes out of a complex, multi-step, multi-sub-contracted manufacturing process. A supplier change that should have been a simple affair has cost us several kilobucks in analyses in the past months. I hate the stuff.

Re: L'Affaire Siloxane

#9

I'm sceptical of the claim that they couldn't eliminate the majority of them from stuff that's shipped up to the ISS. Even if it meant making special space certified hair conditioner.

I don't see why not either, just get "organic"/plant or mineral based cosmetics, deodorants and hair products.

Re: L'Affaire Siloxane

#10
post #7

An interesting substory that is simultaneously reminiscent of the Fogbank story and how Hayek's "curious task" is much more broadly applicable: There is a good cautionary tale here from the Space Shuttle era. That vehicle had heat resistant tiles that had to be attached to the aluminum belly of the orbiter. A special cloth had been certified for wiping the aluminum clean before applying the primer that securely bonde…

In medical device manufacturing you have systems in place that your vendors have to disclose changes to their manufacturing process that hopefully can catch stuff like this before people die. I can see how minute stuff gets easily passed off as not an important change.
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