Earlier quoted context omitted.
For decoding serial one of those $5 logic analyzers is more than sufficient, you don't really need an oscilloscope at all. I don't really like using protocol decoding on my scope unless I need to correlate timing with an analog signal because it's tedious to set up and use for a simple digital signal. https://www.aliexpress.com/item/New-Arrival-USB-Logic-Analyz...
RS232 is 12V, but a couple of resistors would sort that out. If you're a beginner I would actually recommend the Saleae Logic Analyser over this scope, unless your routinely dealing with analog or voltages over 5.5V, the Saleae is much more useful, has serial (and other) decoders built in as opposed to having to pay extra on the Rigol, has better capture and triggers plus as a bonus it doesnt have that noisy fan goin…
I use my scope just often enough that I'm glad I have it, but I sometimes also regret buying it because it's not that often that I actually need it.