The accuracy of GOCR is very high and it doesn't require any learning. http://manpages.ubuntu.com/manpages/dapper/man1/gocr.1.html
GOCR is ok, certainly much better than GNU Ocrad, but I've had much better results with Tesseract.
If you're doing real time street sign recognition or involved with a book scanning and archival startup, investigate Tesseract for sure. But even then you'll probably want to prototype with gocr first.