Earlier quoted context omitted.
I always wondered why in English the constant and the letter π pronounced as /paɪ/ when the Greek letter is obviously /pi/. It really grinds my gears, there's no pie in π! Does Enlgish routinely localize foreign alphabet names? If so, it's bad practice. I believe no one in the world learns English alphabet pronouncing it arbitrary, and not as /ˈeɪ/ /ˈbiː/ /ˈsiː/.
Just a wild guess, but perhaps it's part of a vowel shift either in modern Greek, or modern English. I know UK (bee-ta) and USA (bay-ta) pronounce Beta differently but am slightly ashamed to say I don't know how modern Greeks pronounce it. I understand it's derived from Hebrew's Beth, though? Language is a constant curiosity.
For centuries, and probably still today, the language taught at school was Ancient Greek -- that's where I learnt the pronunciations. I don't know if pi had a similar change in Greek pronunciation.